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During the discharge of a lead storage battery, the density of sulphuric acid fell from 1.294 to 1.139 g mL−1. Sulphuric acid of density 1.294 g mL−1 is 39 % H2SO4 by mass and that of density 1.139 g mL−1 is 20 % H2SO4 by mass. The battery holds 3.5 L of the acid and the volume remained practically constant during the discharge. The charging and discharging reactions arePb+SO2−4→PbSO4+2e− (charging)PbO2+4H++SO2−4+2e−→PbSO4+2H2O (discharging)The number of ampere-hour for which the battery must have been used is

Answer» During the discharge of a lead storage battery, the density of sulphuric acid fell from 1.294 to 1.139 g mL1. Sulphuric acid of density 1.294 g mL1 is 39 % H2SO4 by mass and that of density 1.139 g mL1 is 20 % H2SO4 by mass. The battery holds 3.5 L of the acid and the volume remained practically constant during the discharge. The charging and discharging reactions are

Pb+SO24PbSO4+2e (charging)

PbO2+4H++SO24+2ePbSO4+2H2O (discharging)

The number of ampere-hour for which the battery must have been used is


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