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During the discharge of a lead storage battery, the density of sulphuric acid fell from 1.294 to 1.139 g mL−1. Sulphuric acid of density 1.294 g mL−1 is 39 % H2SO4 by mass and that of density 1.139 g mL−1 is 20 % H2SO4 by mass. The battery holds 3.5 L of the acid and the volume remained practically constant during the discharge. The charging and discharging reactions arePb+SO2−4→PbSO4+2e− (charging)PbO2+4H++SO2−4+2e−→PbSO4+2H2O (discharging)The number of ampere-hour for which the battery must have been used is |
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Answer» During the discharge of a lead storage battery, the density of sulphuric acid fell from 1.294 to 1.139 g mL−1. Sulphuric acid of density 1.294 g mL−1 is 39 % H2SO4 by mass and that of density 1.139 g mL−1 is 20 % H2SO4 by mass. The battery holds 3.5 L of the acid and the volume remained practically constant during the discharge. The charging and discharging reactions are Pb+SO2−4→PbSO4+2e− (charging) PbO2+4H++SO2−4+2e−→PbSO4+2H2O (discharging) The number of ampere-hour for which the battery must have been used is |
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