InterviewSolution
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InterviewSolution
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Explain (a )Which d-orbital in involved in (i) `sp^(3)`d hybridisation (ii) `sp^(3) d^(2)` hybridisation (iii) `dsp^(2)` hybridisation (iv) `sp^(3)d^(3)` hybridisation (b) Why `H_(2)O` is liquid while `H_(2)S` is gas (c ) Why `KHF_(2)` exists but `KHCI_(2)` does not (d) Benzene ring contains alternate single and double bonds yet all the `C-C` bonds are of equal lenght why (e) Out of `P-F,CI-F,S-F` and `F-F` bonds, which bond is the least ionic? . |
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Answer» (i) `dz^(2)` (ii) `dx^(2) -y^(2)` and `dz^(2)` (iii) `dx^(2)-y^(2)` (iv) `dxy,dyz,dxz` (b) Due to intermolecular H-bonding in `H_(2)O` association of `H_(2)O` molecules occurs but in `H_(2)S` there is no H-bonding (d) Due to resonance in benzene (e) `F-F` is the least ionic or more covalent due to the zero `EN` difference in `F-F` atoms Greater the difference in `EN` value of two atoms more ionic is the compound and vice versa . |
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