1.

Explain the following:(a)  Electrovalent compounds conduct electricity.(b) Electrovalent compounds have a high melting point and boiling point while covalent compounds have low melting and boiling points.(c) Electrovalent compounds dissolve in water whereas covalent compounds do not.(d) Electrovalent compounds are usually hard crystals yet brittle.(e) polar covalent compounds electricity.

Answer»

(a) Electrovalent compounds in the solid state do not conduct electricity because movement of ions in the solid state is not possible due to their rigid structure. But these compounds conduct electricity in the molten state. This is possible in the molten state since the electrostatic forces of attraction between the oppositely charged ions become weak. Thus, the ions move freely and conduct electricity.

(b) The atoms of covalent compounds are bound tightly to each other in stable molecules, but the molecules are generally not very strongly attracted to other molecules in the compound. On the other hand, the atoms (ions) in electrovalent compounds show strong attractions to other ions in their vicinity. This generally leads to low melting points for covalent solids, and high melting points for electrovalent solids.

(c) Electrovalent compounds dissolve in polar solvents like water because the forces of attraction between positive and negative charges become weak in water. But since covalent compound are made up of molecules, they do not ionize in water and hence do not dissolve in water.

(d) Since it takes a lot of energy to break the positive and negative charges apart from each other, the ionic compounds are so hard. But on applying stress, Ions of the same charge are brought side-by-side and so the opposite ions repel each other and crystal breaks into pieces.

(e) Since polar covalent compounds are made up of charged particles, they conduct electricity in aqueous solution



Discussion

No Comment Found