InterviewSolution
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Explain the following :(A) Rate of the reaction in terms of the concentration of the reactants. (B) Rate of reaction in terms of the concentration of the products. |
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Answer» (A) Rate of the reaction in terms of the concentration of the reactants : If c1 and c2 are the concentrations of the reactant A at time t1 and t2 respectively, then, the change in concentration, Δc = c2 – c1 Since c2 < c1, The term Δc is negative often written as – Δc. The time interval is, Δt – t2 – t1 If Δ [A] is the change in concentration of A, then A[A] = C2 – C1 ∴ Rate of the reaction = A = \(\frac{-ΔA}{Δt}\) ∴ Rate of the reaction = \(\frac{-Δc}{Δt}\) (B) Rate of the reaction in terms of the concentration of the products : If x1 and x2 are the concentrations of the product B at time t1 and t2 respectively, Then the change in concentration, Δx = x2 – x1. ∴ x2 > x1, The term Δx is positive. The time interval is, Δt = t2 – t1 If ΔB is the change in concentration of product B, Then, Δ[B] = x2 – x1 = Δx ∴ Rate of formation of B = \(+\frac{Δ[B]}{Δt}\) ∴ Rate of the reaction = \(\frac{Δx}{Δt}\) |
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