InterviewSolution
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`FeCr_(2)O_(4)+Na_(2)CO_(3)+O_(2)overset("Fusion")to[X]underset(H_(2)O)overset(H^(+))[Y]underset(H_(2)O_(2))overset(H^(+))to[Z]` Whichf of the following statement is true for the compounds [X], [Y] and [Z]?A. In all three compounds, the chromium is in +6 oxidation stateB. [Z] is a deep blueu-violet coloured compound which decomposes rapidly in aqueous solution into `Cr^(3+)` and dioxygen.C. Saturated solution of [Y] gives bright orange compound, chromic anhydride, with cold and concentrated `H_(2)SO_(4)`.D. All of these. |
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Answer» Correct Answer - D `4FeCr_(2)O_(4)+8Na_(2)CO_(3)+7O_(2)overset(Fusion)Na_(2)overset(+VI)(CrO_(4))underset(H_(2)O)overset(H^(+))toNa_(2)overset(+VI)(Cr_(2))O_(7)underset(H_(2)O_(2))overset(H^(+))to overset(+VI)(Cr)O(O_(2))_(2)` (deep blue violet) `overset(H_(2)O)toO_(2)+H_(2)O+Cr^(3+)`. (X) (Y) (Z) `Na_(2)Cr_(2)O_(7)+H_(2)SO_(4)to2CrO_(3)` (bright orange/red-chromic anhydride) +`Na_(2)SO_(4)+H_(2)O`. |
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