1.

For reaction AtoB, the rate constant k_(1)=A_(1)e^(-Ea)//RT and for the reaction PtoQ, the rate constant k_(2)=A_(2)e^(-Ea_(2))//RT. If A_(1)=10^(8),andEa_(1)=600"cal/mol",Ea_(2)=1200"cal/mol", then the temperature at which k_(1)=k_(2) is (R=2cal/K-mol)

Answer»

600 K
`300xx4.606` K
`(300)/(4.606)K`
`(4.606)/(600)K`

SOLUTION :`A_(1)e-Ea_(1)//RT=A_(2)e-Ea_(2)//RT`
`(A_(2))/(A_(1))=e(Ea_(2)-Ea_(1))//RT`
`10^(2)="Exp"{(600)/(RT)}"R=2cal/K-mol"`
`2" ln "10=(600)/(2T)`
`T={(300)/(2xx2.303)}K""]`


Discussion

No Comment Found

Related InterviewSolutions