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Identify A, B, C, D and E. A while substance A reacts with dilute `H_2SO_4` to produce a colourless gas B and a colourless solution C. The reaction between B and acidified `K_2Cr_2O_7` solution produces a green solution and slightly coloured precipitate D. The substance D burns in air to produce a gas E which reacts with B to yield D and a colourless liquid. Anhydrous copper sulphate is turned blue on adiition of this colourless liquid. Addition of aqueous `NH_3` or `NaOH` to C produces first a precipitate |
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Answer» `ZnS(A)+dil.H_2SO_4rarrH_2S(B)+ZnSO_4(C)` `3H_2S+Cr_2O_7^(2-)+8H^(o+)rarr2Cr^(3+)(Green)+3S(D)+7H_2O` `S(D)+O_2rarrSO_2(E)` `SO_2(E)+H_2S(B)toS(D)+H_2O` (Colourless liquid) `Zn^(2+)+2OH^(ɵ)to2n(OH_2)darroverset(OH^(ɵ))toZn(OH)_4^(2-)` (Clear solution) (C) |
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