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Identify A, B, C, D, and X. When a white crystalline compound X is heated with `K_2Cr_2O_7` and concentrated `H_2SO_4`, a reddish brown gas A is evolved. On passing A into caustic soda solution a yellow coloured solution of B is obtained Neutralising the solution of B with acetic acid and on subsequent addition of lead acetate, a yellow precipitate C is obtained. When X is heated with NaOH solution a colourless gas is evolved and on passing this gas into `K_2Hgl_4` solution a reddish brown precipitate D is formed. |
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Answer» `X` is `NH_4Cl` `4Cl^(ɵ)+K_2Cr_2O_76H_2SO_4tounderset((gas A))(2CrO_2Cl_2+2KHSO_4+4HSO_4^(ɵ)+3H_2O` `CrO_2Cl_2+4NaOHtounderset((B))(Na_2CrO_4+2NaCl+2H_2O` `Na_2CrO_4+(CH_3COOH)_2PbtoPbCrO_4+2NaCl+2H_2O` `NH_4^(o+)+4NaOHoverset(Delta)tounderset((Gas))(NH_3)+Na^(o+)+H_2O` `NH_3+2[HgI_4]^(2-)+H_2OtoH_2N-Hg-O-Hg-Idarr` |
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