1.

If NaCl is doped with 10-3 mol % of SrCl2, what is the concentration of cation vacancies?

Answer»

Since for addition of one Sr2+ ion two Na+ ion need to be displaced i.e. one vacancy will be created for each Sr2+ ion.
Concentration of cation vacancies = Concentration of Sr2+ ion = 6.022 × 1023 × \(\frac { { 10 }^{ -3 } }{ 100 } \) ions/mole of NaCl
= 6.022 × 1018 ions/mole of NaCl
Hence concentration of cation vacancies is 6.022 × 1018 vacancies/mole of NaCl



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