1.

In coal, pyrites `(FeS_(2))` is present as a pollution-causing impurity, which is removed by combustion. `2FeS_(2) + 5O_(2) rarr 4SO_(2) + 2FeO`. A process designed to remove orgainc sulphur from coal prior to combustion involves the reaction. `X - S - Y + 2NaOH rarr X - O - Y + Na_(2)S + H_(2) O` `CaCO_(3) rarr CaO + CO_(2)` `Na_(2)S + CO_(2) + H_(2)O rarr Na_(2) CO_(3) + H_(2) S` `CaO + H_(2)O rarr Ca (OH)_(2)` `Na_(2) CO_(3) + Ca(OH)_(2) rarr CaCO_(3) + 2NaOH` In the processing in 320 metric tons of a coal having 1.0% sulphur content, how much limestone `(CaCO_(3))` must be edecomposed to provied enough `Ca (OH)_(2)` to regenerate the `NaOH` used in the original leaching step?A. 2.0 metric tonB. 4.0 metric tonC. 8.0 metric tonD. 10.0 metric ton

Answer» Correct Answer - D
Weight of `CaCO_(3) = (320 xx 10^(6) g "coal")`
`((1.0 g S)/(100 g "coal"))((1 "mol"S)/(32 g S))`
`((1 "mol" CaCO_(3))/("mol" S))((100 g CaCO_(3))/("mol"CaCO_(3)))`
`= (320 xx 10^(6) xx 1 xx 1 xx 1 xx 100)/(100 xx 32)`
`= 10 xx 10^(6) g CaCO_(3)`
= 10 metric ton `CaCO_(3)`


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