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In presence of HCl, `H_(2)S` results the precipitation of group-2 radicals but not group-4 radicals during qualitative analysis. It is due toA. higher concentration of `H^(+)`B. lower concentration of `H^(+)`C. higher concentration of `S^(2-)`D. lower concentration of `S^(2-)` |
Answer» Correct Answer - D Dissociation of `H_(2)S` is suppressed in presence of HCl due to common ion effect. This decreases the `S^(2-)` ion concentration and hence only group 2 radicals are precipitated as they have low solubility products. |
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