1.

Match the transformation in Column I with appropriate options is Column II `{:(,"Column I",,"Column II"),((A),CO_(2)(s)rarrCO_(2)(g),(p),"Phase transition"),((B),CaCO_(3)(s)rarrCaO(s)+CO_(2),(q),"Allotropic change"),((C),2H• rarrH_(2)(g),(r),DeltaH" is positive"),((D),P_(("white,solid"))rarrP_(("red,solid")),(s),DeltaS" is positive"),(,,(t),DeltaS " is negative"):}`

Answer» Correct Answer - A `rarr` p, r, s; B `rarr` r, s; C `rarr` t ; D `rarr`p, q, t
(A) `CO_(2)(s)rarrCO_(2)(g)`
It is phase transition. The process is endothermic (sublimation). Gas is produced, so entropy increases.
(B) On heating `CaCO_(3)` decomposes, So, process is endothermic. The entropy increases as gaseous product is formed.
(C) `2H•rarrH_(2)(g)`
Entropy decreases as number of gaseous particles decreases.
(D) It is phase transition
White and red P are allotropes
Red P is more stable than white ,brgt So `DeltaG` is -ve


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