1.

p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of aqueous solution of Y with reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, the treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z. Q. Compound Z isA. `Mg_2[Fe(CN)_6]`B. `Fe[Fe(CN)_6]`C. `Fe_4[Fe(CN)_6]_3`D. `K_2Zn_3[Fe(CN)_6]_2`

Answer» Correct Answer - B
`4FeCl_3+3K_4[Fe^(2+)(CN)_6]toFe_4[Fe(CN)_6]_3+2KCl`
`FeCl_3+K_3[Fe^(3+)(CN)_6]toFe[Fe(CN)_6]+3KCl`


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