

InterviewSolution
Saved Bookmarks
1. |
p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of aqueous solution of Y with reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, the treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z. Q. Compound Z isA. `Mg_2[Fe(CN)_6]`B. `Fe[Fe(CN)_6]`C. `Fe_4[Fe(CN)_6]_3`D. `K_2Zn_3[Fe(CN)_6]_2` |
Answer» Correct Answer - B `4FeCl_3+3K_4[Fe^(2+)(CN)_6]toFe_4[Fe(CN)_6]_3+2KCl` `FeCl_3+K_3[Fe^(3+)(CN)_6]toFe[Fe(CN)_6]+3KCl` |
|