1.

Standard electrode potential data are useful for understanding the suitability of an oxidant in a redox Titration. Some half – cell reactions and their standard potential are given below: MnO−4(aq)+8H+(aq)+5e−→Mn2+(aq)+4H2O(I); E∘=1.51 V Cr2 O2−7 (aq)+14H+(aq)+6e−→2Cr3+(aq)+7H2O(I); E∘=1.38V Fe3+(aq)+e−→Fe2+(aq); E∘=0.77V Cl2(g)+2e−→2Cl−(aq); E∘=1.40V Identify the only incorrect statement regarding the quantitative estimation of aqueous Fe(NO3)2.

Answer»

Standard electrode potential data are useful for understanding the suitability of an oxidant in a redox Titration. Some half – cell reactions and their standard potential are given below:
MnO4(aq)+8H+(aq)+5eMn2+(aq)+4H2O(I); E=1.51 V
Cr2 O27 (aq)+14H+(aq)+6e2Cr3+(aq)+7H2O(I); E=1.38V
Fe3+(aq)+eFe2+(aq); E=0.77V
Cl2(g)+2e2Cl(aq); E=1.40V

Identify the only incorrect statement regarding the quantitative estimation of aqueous Fe(NO3)2.



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