1.

The `pK_(a)` of a weak acid `(HA)` is `4.5`. The `pOH` of an aqueous buffered solution of `HA` in which `50%` of the acid is ionized is:A. `4.5`B. `2.5`C. `9.5`D. `7.0`

Answer» Correct Answer - C
For buffer solution :
`pH= pK_(a)+log (["Salt"])/(["Acid"])= 4.5+log (["Salt"])/(["Acid"])`
As HA is `50%` ionised, so [Salt] = [Acid]
`pH = 4.5`
`pH+pOH=14`
`:. pOH= 14-4.5 = 9.5`


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