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Transition metals usually from coloured complexes and d-d transitions `(t_(2g)hArre_(g))` are responsible for colour as the energy difference between `t_(2g)` and `e_(g)` lies in visible region. But all the coloured ions are not dut to d-d transition but charge transfer bands also play important roles. Charge transfer bands may be of two types. (i) ligand to metal (CTLM)`" "(ii)` metal to ligand (CTML). Charge transfer transition always produces intense colour as compared to d-d transition. `MnO_(4)^(-)` is dark purple coloured though Mn is in `(+VII)` oxidation state with `3d^(@)` configurationA. due to d-d transitionB. due to CTML spectraC. due to CTLM spectraD. None of these |
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Answer» Correct Answer - C Conceptual |
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