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What is a periodic property? How do the following properties change in a group and period? Explain. I. a) Atomic radius b) Ionization energy c) Electron affinity d) Electronegativity II. Explain the ionization energy order in the following sets of elements:a) Na, Al, Cl b) Li, Be, B c) C, N, O d) F, Ne, Na e) Be, Mg, Ca |
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Answer» Periodic property: The property in which there shall be a regular gradation is called periodic property. I. a) Atomic radius : Period : Atomic radius of elements decreases across a period from left to right because the nuclear charge increases due to increase in atomic number. Group : Atomic radius increases from top to bottom in a group due to addition of new shell. b) Ionization energy: Period : When we move from left to right it does not follow a regular trend but generally increases due to increase in atomic number. Group : In a group from top to bottom, the ionization energy decreases due to increase in atomic size. – c) Electron affinity: Period : Electron affinity values increase from left to right in a period. Group : Electron affinity values decrease from top to bottom in a group. d) Electronegativity : Period : Electronegativity increases from left to right in a period. Group : Electronegativity decreases from top to bottom in a group. II. Ionization energy order : a) Na, Al, Cl : In a period ionisation energy increases so the order is Na < kl < Cl. b) Li, Be, B : Beryllium has stable configuration 1s² 2s². So it has more ionisation energy. So the order is Li < B < Be. c) C, N, O : Nitrogen has half-filled p-orbitals. So it has greater ionisation energy. So the order is C < O < N. d) F, Ne, Na : Ne is inert gas right to F. Whereas Na is a metal ion in third period. So, the order is Na < F< Ne. e) Be, Mg, Ca : In a group ionisation energy decreases. So the order is Be > Mg > Ca. |
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