1.

0.01 solution of NaCl offered a resistance of 200 Ohm in a conductivity cell at 298 Kelvin if the cell constant of the cell is unity calculate molar conductivity of the solution.

Answer»

Answer:

Given:

  1. Molarity (M) = 0.01 M
  2. Resistance (R) = 200 Ω
  3. CELL CONSTANT = 1 cm⁻¹

Explanation:

\rule{300}{1.5}

We Know from the formula,

Cell constant = κ × R

Here,

  • κ Denotes conductivity.
  • R Denotes resistance.

⇒ 1 = κ × 200

⇒ κ = 1/200

κ = 1/200 S cm⁻¹

Conductivity (κ) of the solution is 1/200 S cm⁻¹.

\rule{300}{1.5}

\rule{300}{1.5}

From the formula we know,

\bigstar\;\underline{\boxed{\sf \Lambda_{m}=\dfrac{\kappa \times 1000}{M}}}

Here,

  • κ Denotes conductivity.
  • M Denotes Molarity.

Substituting the values,

\longrightarrow\sf \Lambda_{m}=\dfrac{\frac{1}{200} \times 1000}{0.01}\\\\\\\longrightarrow\sf \Lambda_{m}=\dfrac{1\times 1000}{200\times 0.01}\\\\\\\longrightarrow\sf \Lambda_{m}=\dfrac{1000}{2}\\\\\\\longrightarrow\sf \Lambda_{m}=500\\\\\\\longrightarrow \large{\underline{\boxed{\red{\sf \Lambda_{m}=500\;Scm^{2}mol^{-1}}}}}

Molar Conductivity of the solution is 500 S cm² mol⁻¹.

\rule{300}{1.5}



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