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0*1 mole of N_(2)O_(4) (g) was sealed in a tube under atmospheric conditions at 25^(@)C. Calculate the number of moles of NO_(2) (g) present if the equilibrium N_(2)O_(4) (g) hArr 2 NO_(2)is reached after some time (K_(p) = 0 *14). |
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Answer» Solution :` {: (,N_(2)O_(4)(G),hArr,2NO_(2)(g),) ,("Intial amounts",0.1 "mole",,0,), ("At equilibrium " ,(0*1 -x),,2x," TOTAL " 0*1 +x "moles"):}` As P=1atm, ` p_(N_(2)O_(4)) = (0*1 -x)/(0*1 +x), p_(NO_(2))= 2/(0*1 + x) atm ` ` K_(p) - (p_(N_(O_(4)))^(2))/p_(N_(2)O_(4)) = (2x // (0*1 + x))^(2)/((0*1-x) //( 0*1 +x))= (4x^(2))/((0*1- x) ( 0*1 +x) )= (4x^(2))/(0*01 - x^(2) )` ` :. (4x^(2))/(0*01 - x^(2) = 0*14 )or 4*14x^(2) = 0*0014or x = 0* 018 ` ` :. " No. of moles of " NO_(2) " at equilibrium " = 2x = 2 xx 0* 018= 0* 036 "mole" ` |
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