1.

0.3 g of an organic compound on Kjeldahl’s analysis gave enough ammonia to just neutralise 30 mL of 0.1N H2SO4 . Calculate the percentage of nitrogen in the compound.

Answer»

Weight of organic compound (w) = 0.3 g

Strength of sulphuric acid used (N) = 0.1 N

Volume of sulphuric acid used (V) = 30 mL

30 ml of 0.1 N sulphuric acid = 30 ml of 0.1 N ammonia

Percentage of nitrogen = \(\Big(\frac{14\times NV}{1000\times w}\Big)\)x 100

\(\Big(\frac{14\times0.1\times30}{1000\times0.3}\Big)\)x 100 = 14%



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