1.

0.5 litre of an ideal gas at a pressure of 20 atm expands to a final volume of 0.5 m ^(3). The process obeys the equation PV = a constant, (i) Find the value of this constant (ii) What is the final pressure ? And (iii) Find, the work done by the gas,

Answer»

SOLUTION :`V _(1) = 0.5` liter `= 0.5 xx 10 ^(-3) m ^(3)`
` P _(1) = 20 atm = 20 xx 101325 Pa`
`V _(2) =- 0.5 m ^(3)`
`P _(2) = ?`
`PV = P _(1) V _(1) = P _(2) V _(2)`
` P _(1) V _(1) = 20 xx 101325 xx 0.5 x 10^(-3)`
`P _(2) = ( P _(1) V _(1))/( V _(2)) = ( 20 xx 0.5 xx 10 ^(-3))/( 0.5)`
`= 0. 020 atm`
Work done `W = RT log _(e) "" (T _(2))/( V _(1))`
But `RT = P _(1) V _(1) = P _(2) V _(2)`
` W = 2. 303 P _(1) V _(1) log _(10) "" (V _(2))/( V _(1))`
` 2. 303 xx 20 xx 101325 xx 0.5 xx 10^(-3) xx 0.5 xx 10 ^(-3) xx log _(10) " "(0.5)/( 0.5 xx 10 ^(-3))`
`= 2. 33 xx 10 ^(6) J`


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