1.

0.532 g of the chloroplatinate of a diacid base gave 0.195 g of the platinum residue on ignition. Calaculate the molecular mass of the base.

Answer»

Solution :Mass of the base chloroplatinate taken `(W) = 0.532 G`
Mass of the platinum residue `(x) = 0.195 g`
step I. Equivalent mass of the base
Equivalent mass of the base `= (1)/(2) [(W)/(x) xx 195 - 410] = (1)/(2) [(0.532)/(0.195) xx 195 - 410]`
`= (1)/(2) [532 - 410] = 61`
Step II. Molecular mass of the base
Molecular mass of the base = Equivalent mass `xx` ACIDITY `= 61 xx 2 = 122`


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