1.

0.759 g of silver salt of a dibasic acid was ignited to form 0.463 g of the silver residue. Calculate the molecular mass of the acid.

Answer»

Solution :Step 1: EQUIVALENT MASS of silver salt of the acid.
Equivalent mass of silver salt of the acid `= ("Mass of silver salt")/("Mass of silver residue") xx 108`
`= (0.759)/(0.463) xx 108 = 177`
Step II. Equivalent mass of acid
Equivalent mass of acid `=` Equivalent mass of silver salt - Equivalent mass of Ag + Equivalent mass of H
`= 177 - 108 + 1 = 70`
Step III. Molecular mass of acid
Molecular mass of acid = Equivalent mass `xx` basicity
`= 70 xx 2 = 140`


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