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1.0g ofa samplecontaining NaCl, KCl and some inert impurity is dissolvedin excess of water and treated with excess of AgNO_(3) solution. A 2.0 g precipitate to AgCl separate out. Also sample is 23% by mass in sodium. Determine mass percentage of KCl in the sample :

Answer» <html><body><p><br/></p>Solution :Moles of `NaCl`in <a href="https://interviewquestions.tuteehub.com/tag/sample-1194587" style="font-weight:bold;" target="_blank" title="Click to know more about SAMPLE">SAMPLE</a> `=0.01` = moles of `AgCl` from `NaCl` in <a href="https://interviewquestions.tuteehub.com/tag/precipitate-1162804" style="font-weight:bold;" target="_blank" title="Click to know more about PRECIPITATE">PRECIPITATE</a> `=0.01`<br/> Total moles of `AgCl` precipitate `=(<a href="https://interviewquestions.tuteehub.com/tag/2-283658" style="font-weight:bold;" target="_blank" title="Click to know more about 2">2</a>)/(143.5)=0.01393`<br/> implies Moles of `AgCl` from `<a href="https://interviewquestions.tuteehub.com/tag/kcl-527837" style="font-weight:bold;" target="_blank" title="Click to know more about KCL">KCL</a> = 0.00393` = moles of `KCl` <br/> implies Mass of `KCl` in sample `=0.00393xx74.5=0.2928g` <br/> Mass `%` of `KCl` in the sample `=29.28`</body></html>


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