1.

(1) Give electronic configuration of the following species and show which of these contain same number of electrons: Cl^(-),N^(3-),P^(3-),K^(+),Na^(+),Mg^(2+),Ar,S^(2-),Ne,O^(2-),Al^(3+),Ca^(2+). (2) In an atom of an inert gas, the difference between the number of p-electrons and s-electrons is equal to the number of d-electrons present in that atom. identify the inert gas and indicate its atomic number.

Answer»

SOLUTION :(1)
So, `N^(3-),Na^(+),Mg^(2+),O^(2-)Ne,Al^(3+)` have the SAMME number of electrons (10), so they are isoelectronic. Electronic configuration of each of them `1S^(2)2S^(2)2p^(6)`.
Again, `Cl^(-),P^(3-),K^(+),Ar,S^(2-)` and `Ca^(2+)` have the same number of electrons (18), so they are isoelectronic. their electronic configuration is:
`1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)`
(2) The inerrt gas is krypton (Kr) whose atomic number is 36, has electronic configuration:
`1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)3d^(10)4S^(2)4p^(6)`
Total number of s-electrons=8 and total number of p-electrons=18
`therefore`Difference in the number of s and p- electrons
`therefore`Difference in the number of s and p-electrons=18-8=10=number of d-electrons.


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