1 mole each of FeC_(2)O_4and FeSO_4is oxidised separately by 1M KMnO_4in acid medium. Calculate the volume ratio of KMnO_4used for FeC_(2) O_4 and FeSO_4

1 mole each of FeC_(2)O_4and FeSO_4is oxidised separately by 1M KMnO_4

1.	1 mole each of FeC_(2)O_4and FeSO_4is oxidised separately by 1M KMnO_4in acid medium. Calculate the volume ratio of KMnO_4used for FeC_(2) O_4 and FeSO_4
Answer» Solution :`Fe^(2+)+C_(2)O_(4)^(2-) rarrFe^(3+)+2CO_(2)^(4-)+3e` `Fe^(2+) +SO_(4)^(2-) rarrFe^(3+)+SO_(2)^(4-)e` `Mn^(7+)+5erarrMn^(2+)` Meq.of `F_(e)C_(2)O_4` = Meq.of `KMnO_4` `1xx3xx1000=1xx5xxV_(1).......(1)` Meq.of `FeSO_(4)` = Meq.of `KMnO_4` `1xx1 xx1000=1xx5xxV_2""....(2)` By EQ.(1) and (2) `V_1/V_2=3`