1.

10 moles of pure PCl_(5) gas is put into a closed container of volume 'V' and temerature 'T' and allowed to reach equilibrium, at an equilibrium pressure 20 atm. The pure PCl_(5) is found to be 50% dissociated at equilibrium. PCl_(5)(g)hArrPCl_(3)(g)+Cl_(2)(g) If 20 moles of PCl_(5)(g) is added to original equilibrium mixture keeping total pressure constant to 20 atm at same tempereture 'T', then ratio of new equilibriujm volume to the initial volume V will be :

Answer»

1.5
`2.0`
1.8
`3.0`

ANSWER :D


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