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100 ml 0.1 M H_3PO_4 solution is being titrated with 0.1 M NaOHsolution. The pH of the reaction mixture keeps increasing with addition of NaOH. The successive dissociation constant of H_3PO_4 " are "10^(-3) , 10 ^(-6) and 10^(-14)respectively. What is the pH of the reaction mixture after adding 50 ml of NaOH ? |
Answer» <html><body><p>`3`<br/>`<a href="https://interviewquestions.tuteehub.com/tag/4-311707" style="font-weight:bold;" target="_blank" title="Click to know more about 4">4</a>`<br/>`<a href="https://interviewquestions.tuteehub.com/tag/6-327005" style="font-weight:bold;" target="_blank" title="Click to know more about 6">6</a>`<br/>`5.3`</p>Solution :After <a href="https://interviewquestions.tuteehub.com/tag/adding-2399902" style="font-weight:bold;" target="_blank" title="Click to know more about ADDING">ADDING</a> <a href="https://interviewquestions.tuteehub.com/tag/50-322056" style="font-weight:bold;" target="_blank" title="Click to know more about 50">50</a> ml NaOH, buffer ` (H_3PO_4 + NaH_2 PO_4) ` with <a href="https://interviewquestions.tuteehub.com/tag/maximum-556915" style="font-weight:bold;" target="_blank" title="Click to know more about MAXIMUM">MAXIMUM</a> capacity is obtained. <br/> ` therefore pH =P^(Ka_2) =3`</body></html> | |