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13. The equivalent weight of MnCl2 is half of itsmolecular weight when it is converted to

Answer»

net oxidation state of Mn in MnCl2 is Mn+(Cl2)=0

so,Mn+(-1)2=0 (net charge of Cl=-1

Mn=2

now net charge of Mn in MnO2=

Mn+(-2)2 (net charge on O=-2

Mn=4

MnCl2-----MnO2

equivalent weight =molecular weight (let M)/change in the oxidation state

equivalent weight=M/(4-2)

=M/2

Thus equivalent weight of MnCl2 is half the molecular weight when it is converted to MnO2



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