1.

25 ml of a solution containing HCl and `H_(2)SO_(4)` required 10 ml of 1 M NaOH solution for complete neutralization. 20 ml of the same acid mixture on being treated with excess of `AgNO_(3)` gives Report your answer as `(x+y)xx1000.`

Answer» Let molarity of HCl is x and `H_(2)SO_(4)` is y
`{:( m" mole " " m mole "),( x xx25" "+" "2yxx25=10xx1),(" "underbrace(" ")),(" " m" mole of " [H^(+)]):}`
Applying POAC
Applying POAC
`(20xxx)/(1000)=(0.1435)/(143.5)=10^(-3)`
`x=(1)/(20)=0.05M`
`y=(8.75)/(50)=0.175M`
` therefore(x+y)xx1000=(0.05+0.175)xx1000=225`


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