1.

(a) A powdered substance (A) on treatment with fusion mixturegives a green coloured compound (B). (b) The solution of (B) on acidification with hot dilute H_(2)SO_(4) gives a pink coloured compound (C). (c) The aqueous solution of (A) on treatement with excess of NaOH and bromine water gives a compound (D). (d) A solution of (D) in conc. HNO_(3) with lead dioxide at boiling temperature produces a compound (E), which has of the same colour as that of (C). (e) A solution of (A) in dilute HCI on treatment with a solution of barium chloride gave a white precipitate of compound (F), which was insoluble in conc. HNO_(3) and conc. HCI. What is (D)?

Answer»

`MnO_(2)`
`FeS`
`Na_(2)MnO_(4)`
`MnO`

Solution :(A) `MnSO_(4)` (B) `Na_(2)MnO_(4)` (C) `HMn_(4)`
(D) `MnO_(2)` (E) `HMnO_(4)` (F) `BaSO_(4)`


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