1.

A block of quartz of mass 13.5 g is weighed in aniline at 0^(@)Cand100^(@)C. The weighings are 8.905 g and 9.29 g respectively, Calculate the coefficient of cubicat expansion of aniline, assuming the coefficient of cubical expansion of quartz to be zero.

Answer»

SOLUTION :We know the ratio of thrusts or loss of weight in liquid is
`W_(2)/W_(1)=(Th.)/(Th)=(V^(1)sigma^(1)g)/(Vsigmag)=((1+gamma_(s)Deltatheta))/((1+gamma_(L)Deltatheta))=1/((1+gamma_(L)Deltatheta))`
`thereforegamma_(s)=0`
In this problem, `W_(1)=(13.5-8.905)xx10^(-3)xxgN`
= `4.595xx10^(-3)xxgN,t_(1)=0^(@)C,`
`W_(2)=(13.5-9.29)xx10^(-3)xxgN`
= `4.21xx10^(-3)xxgN,t_(2)=100^(@)C,gamma_(s)=0`
Substituting in the above equation.
`(4.21)/(4.595)=1/(1+gamma_(L)100)rArr1+gamma_(L)100=4.595/4.21`
`gamma_(L)=0.385/(4.21xx100)=9.166xx10^(-4)//""^(@)C`


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