1.

(a) Both assertion and reason are correct and the reason is correct expansion to assertion. (b) Both assertion and reason are correct but reason is not the correct expansion of assertion (c) Assertion is correct but reasion is wrong (d) Assertion is incorrect but reason is correct. Q. Assertion: `Phoverset(c+)(N)_2Br^(Theta)` is more acidic than `NH_4Br`. Reason: `PhNoverset(c+)(H)_3` (anilinium ion) is resonance stabilised.

Answer» `NH_3` is a stronger base than aniline, therefore, the conjugate acid of aniline (i.e., `Phoverset(c+)(N)H_2)` is more acidic than the conjugate acid of `NH_3` (i.e., `overset(c+)(N)H_3` ion).


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