1.

A coloured solution known to contain two metal ions of different groups, was treated with excess cold sodium hydroxide solution. When filtered a whitish solid, slowly changing to brown, was retained on the filter paper and a colourless solution collected as the filtrate. Drop wise adition of hydrochloric acid to the filtrate produced a white precipitate which dissolved in excess acid. Treatment of the residue from the filter paper with a strong oxidiser, PbO_(2) and concentratedHNO_(3) on boiling produced a reddish-violet (purple) solution. Filtrate obtained after separation of white solid contains:

Answer»

`[AI(OH)_(4)]^(-)`
`AI_(2)O_(3)`
`MNO`
`Na_(2)MnO_(2)`

Answer :A


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