A coloured solution known to contain two metal ions of different groups, was treated with excess cold sodium hydroxide solution. When filtered a whitish solid, slowly changing to brown, was retained on the filter paper and a colourless solution collected as the filtrate. Drop wise adition of hydrochloric acid to the filtrate produced a white precipitate which dissolved in excess acid. Treatment of the residue from the filter paper with a strong oxidiser, `PbO_(2)` and concentrated `HNO_(3)` on boiling produced a reddish-violet (purple) solution. Reddish-violet (purple) solution is decolourised by:A. both `SO_(3)^(2-),Fe^(2+)`B. both `SO_(4)^(2-),Fe^(3+)`C. both `NO_(3)^(-),Fe^(2+)`D. both `H_(2)O_(2),HCO_(3)^(2-)`

A coloured solution known to contain two metal ions of different group

1.	A coloured solution known to contain two metal ions of different groups, was treated with excess cold sodium hydroxide solution. When filtered a whitish solid, slowly changing to brown, was retained on the filter paper and a colourless solution collected as the filtrate. Drop wise adition of hydrochloric acid to the filtrate produced a white precipitate which dissolved in excess acid. Treatment of the residue from the filter paper with a strong oxidiser, `PbO_(2)` and concentrated `HNO_(3)` on boiling produced a reddish-violet (purple) solution. Reddish-violet (purple) solution is decolourised by:A. both `SO_(3)^(2-),Fe^(2+)`B. both `SO_(4)^(2-),Fe^(3+)`C. both `NO_(3)^(-),Fe^(2+)`D. both `H_(2)O_(2),HCO_(3)^(2-)`
Answer» Correct Answer - A

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