1.

A Compound (A) with molecular formula C_(2)H_(3)N on acid hydrolysis gives (B) which reacts with thionylchloride to give compound ( C). Benzene reacts with compound ( C) in presence of anhydrous AlCl_(3) to give compound (D). Compound (D) on reduction gives (E). Identify (A), (B), ( C), (D) and (E). Write the equations.

Answer»

Solution :COMPOUND with molecular formula ` C_(2)H_(3)N " is " CH_(3)CN(A)` acetonitrile or Methylcyanide.
`underset(" (A) Methyl cyanide")CH_(3)CN overset(H_(2)O) underset(H^(+))tounderset(" (B) Acetic acid")(CH_(3) COOH) `
Acidhydrolysisof nitriliesgive the correspondingcarboxylicacid.
`underset(" (B) Acceticacid") (CH_(3)COOH) + underset("Thionyl chloride")(SoCI_(2)) tounderset("Acetylchloride")( CH_(3)COCI + SO_(2) + HCI`

(A) ` CH_(3) CN `= acetonitrile
(B) ` CH_(3)COOH` =acetic acid
(C) `CH_(3) COCI ` = acetylchloride
(D) `C_(6)H_(5)COCH_(3) ` =acetylchloride
(E) Depending upon the reducing agent
(E) is ` C_(6) H_(5)CHOHCH_(3) to `Phenylmethylcarbinol
(OR)
` C_(6)H_(5)CH_(2)CH_(3) to`EthylBenzene


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