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A gaseous sample is generally allowed to do only expansion//compression type work against its surroundings The work done in case of an irreversible expansion ( in the intermediate stages of expansion//compression the states of gases are not defined). The work done can be calculated using dw= -P_(ext)dV while in case of reversible process the work done can be calculated using dw= -PdV where P is pressure of gas at some intermediate stages. Like for an isothermal reversible process. Since P=(nRT)/(V), so w=intdW= - underset(v_(i))overset(v_(f))int(nRT)/(V).dV= -nRT ln(V_(f)/(V_(i))) Since dw= PdV so magnitude of work done can also be calculated by calculating the area under the PV curve of the reversible process in PV diagram. In the above problem |
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Answer» work done by the gas in `I^(ST)` SAMPLE `gt` work done by gas in `II^(nd)` sample |
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