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A hydrocarbon P has molecular formula C_8H_(16), and it does not undergo hydrogenation with raney Ni. A on free radical chlorination yields three monochloro derivatives Q, R and S (all structural isomers) with their molecular formula C_8 H_(15)Cl. Only Q can show optical isomerism R. On further chlorination produces a dichloride C_8 H_(14) Cl_2, as one of the several isomers which on heating with sodium metal in etheral solution gives bicyclo [2, 2, 2] octane. Which of the following satisfy the criteria for P?

Answer» <html><body><p><img src="https://doubtnut-static.s.llnwi.net/static/physics_images/AKS_TRG_AO_CHE_XI_V01_D_C04_E01_032_O01.png" width="30%"/> <br/><img src="https://doubtnut-static.s.llnwi.net/static/physics_images/AKS_TRG_AO_CHE_XI_V01_D_C04_E01_032_O02.png" width="30%"/> <br/><img src="https://doubtnut-static.s.llnwi.net/static/physics_images/AKS_TRG_AO_CHE_XI_V01_D_C04_E01_032_O03.png" width="30%"/> <br/><img src="https://doubtnut-static.s.llnwi.net/static/physics_images/AKS_TRG_AO_CHE_XI_V01_D_C04_E01_032_O04.png" width="30%"/> </p>Solution :It <a href="https://interviewquestions.tuteehub.com/tag/gives-1007647" style="font-weight:bold;" target="_blank" title="Click to know more about GIVES">GIVES</a> three positioned <a href="https://interviewquestions.tuteehub.com/tag/isomers-1052476" style="font-weight:bold;" target="_blank" title="Click to know more about ISOMERS">ISOMERS</a> on <a href="https://interviewquestions.tuteehub.com/tag/mono-11612" style="font-weight:bold;" target="_blank" title="Click to know more about MONO">MONO</a> <a href="https://interviewquestions.tuteehub.com/tag/chlorination-15933" style="font-weight:bold;" target="_blank" title="Click to know more about CHLORINATION">CHLORINATION</a><br/> <img src="https://doubtnut-static.s.llnwi.net/static/physics_images/AKS_TRG_AO_CHE_XI_V01_D_C04_E01_032_S01.png" width="80%"/></body></html>


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