1.

A metal complex Cr(NH_(3))_(4)Cl_(2) having molar conductivity corresponding to 1:1 electrolyte have been isolated in two Forms (X) and (Y), (X) reacts with AgNO_(3) giving white precipitate which turns yellow on reaction with sodium arsenite whereas (Y) gives a yellow precipitate soluble in concentrate NH_(4)OH Which of the following statements is true for the complex (Y) ?

Answer»

Its trans form is non-planar
Its IUPAC name is tetraaminedichloridochromate(III) bromide.
Its 'spin only' magnetic moment is 3.83 BM.
All of these

Solution :`underset(d^(3))(X) to underset(d^(2)sp^(3))[CR(NH_(3))_(4)ClBr]Cl,(Y) to underset(d^(2)sp^(3),mu=3.8 B.M.)[Cr(NH_(3))_(4)Cl_(2)]Br`
`"EAN" to 24-3+12=33`
Both X and Y can show G.I.


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