1.

A(OH)_(2)is a partially soluble substance and its K_(sp)value is 4 xx 10^(-12) . Which of the following statement is / are correct ?

Answer»

The solubility is unaffected by pH of the MEDIUM
Its solubility increases in a bufferedmediumhaving pH = 2
Its solubility decreases in a buffered medium having pH= 9
Its saturated solution has pH =10.3

Solution :` A(OH) _2 HARR A^(+2) +2OH^(-) `
` "" S "" 2S `
` 4 xx 1 0^(_12) =4S ^(3) rArr S =1 0 ^(_4) M`
` [OH^(-)] = 2 xx 10^(_4)M`
` pOH =4- log 2 = 3.7 rArr pH =10.3`


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