1.

(a) Out of`Ag_(2)SO_(4), CuF_(2), MgF_(2)` and CuCl, which compound will be coloured and why ? (b) Explain `: ` (i)`CrO_(4)^(2-)` is a strong oxidizing agent while `MnO_(4)^(2-)` is not (ii) Zr and Hf have identical sizes. (iii) The lowest oxidation state of manganese is basic while the highest is acidic. (iv) Mn (II) shows maximum paramagnetic character amongst the divalent ions of the first transition series.

Answer» (a) `CuF_(2)` (b) (i) Cr in `CrO_(4)^(2-)` is in the highest oxidation state, i.e., `+6` while Mn in `MnO_(4)^(2-)` is in oxidation state`+6` and its most stable oxidation state is`+7` (ii) due to lanthanoil contraction (iv) `Mn^(2+)` has `3d^(5) ` configuration


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