1.

A solid body of constant heat capacity 1 J//^(@)C is being heated by keeping it in contact with reservoirs in two ways: (i) Sequentially keeping in contact with 2 reservoirs such that each reservoir supplies same amount of heat . (ii) Sequentially keeping in contact with 8 reservoirs such that each reservoir supplies same amount of heat . In both the cases body is brought from initial temperature 100^(@)C to final temperature 200^(@)C. Entropy change of the body in the two cases respectively is

Answer»

1n 2, 4 1n 2
1n 2, 1n 2
1n 2, 21n 2
21n 2, 81n 2

Solution :`100^(@)C = 373 K, 200^(@)C = 473 K`
Increase in temperature = `100^(@)C = 100 K`
Heat CAPACITY, `C = 1 J//K`
(i) For each heat reservoir,
increase in temperature = `100/2 = 50 K`
So, entropy change,
`Delta S_(1) = C[int_(373)^(423) (DT)/(T) + int_(423)^(473) (dT)/(T)]`
`= 1n (423)/(373) + 1n (473)/(423)`
`= 1n(473)/(373)`
(ii) For each heat reservoir,
increase in temperature = `100/8 = 12.5 K`
So, entropy change,
`Delta S_(2) = C[int_(385.5)^(373) (dT)/(T) + .....+ int_(473)^(460.5) (dT)/(T)]`
` = 1n(473)/(373)`
[Note: The VALUES of `Delta S_(1) and Delta S_(2)` does not match any of the given answers. if we take the temperatures to be 100 K and 200 K instead of `100^(@)C and 200^(@)C`, then
`Delta S_(1) = Delta S_(2) = 1n2 J`.


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