1.

A solution of 0.1(N) KCl offers a resistance of 245 ohms. Calculate the specific conductance and the equivalent conductance of the solution if the cell constant is 0.571 cm-1 .

Answer»

Resistance = 245 ohms

∴ Conductance = \(\frac{1}{245} ohm^{-1}\)

Conc. of Constant = 0.571 cm-1

Conc. of solution = 0.1 N

Specific conductance (K) = Observed conductance x Cell constant

\(\frac{1}{245}\times o.571\) = 0.00233061 ohm-1cm-1

Equivalent conductance (eq)

 = \(\frac{k\times1000}{C_{eq}}\) = \(\frac{0.00233061\times1000}{0.1}\)

= 23.3061 ohm-1 cm2eq-1



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