1.

A solution of NaOH is 4g/l. What volume of HCl gas at STP will neutralise, 50 ml of the alkali solution?

Answer»

Molar mass of NaOH = 40 g/mole 

First we have to calculate the mass of NaOH. 

As, 1L of solution contains 4 g of NaOH 

So, 0.05 L of solution contains 4 x 0.05 = 0.2 g of NaOH 

The mass of NaOH = 0.2 g 

Now we have to calculate the moles of NaOH. 

The moles of NaOH = Mass of NaOH/ Molar mass of NaOH = (0.2 g)/(40g/mole) =  0.005 mole 

The moles of NaOH = 0.005 mole

Now we have to calculate the moles of HCl. 

The balanced chemical reaction will be, 

NaOH + HCl ---> NaCl + H2O

From the balanced reaction we conclude that 

As, 1 mole of NaOH neutralizes 1 mole of HCl 

So, 0.005 mole of NaOH neutralizes 0.005 mole of HCl 

The moles of HCl = 0.005 mole 

Now we have to calculate the volume of HCl. 

As we know that at STP, 

1 mole of HCl contains 22.4 L volume of HCl 

So, 0.005 mole of HCl contains 22.4 x 0.005 = 0.112L = 112 ml volume of HCl 

Therefore, the volume of HCl gas at STP will be, 0.112 L or 112 ml.



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