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A solution when diluted with `H_(2)O` And bolled gives a white precipitate .On the addition of excess `NH_(2)CINH_(4)OH` the volume of the precipitate decreases leavingg bebind a white ge3lationtious precipitate identify the precipitate which dissolves in `NH_(4)OH//NH_(4)Cl` :A. `Zn(OH)_(2)`B. `Al(OH)_(3)`C. `Mg(OH)_(2)`D. `Ca(OH)_(2)` |
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Answer» Correct Answer - a `Zn^(2+) + 2H_(2)O rarr underset(white)(Zn(OH)_(2) darr) + 2H^(oplus)` `Zn(OH)_(2) + 2NH_(4)CI + 2NH_(4)OH rarr underset("soluble")([Zn(NH_(3))_(4)]CI_(2)) + 4H_(2)O` `Zn(OH)_(2)` precipitate dissolves in excess of `NH_(4)OH` in the presence of `NH_(4)CI` to form tetrqamine soluble complex |
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