1.

(a) What is a homologous series ? Explain with an example.(b) State two characteristics of a homologous series.(c) The molecular formula of an organic compound is C18H36 . Name its homologous series.(d) What is meant by ‘heteroatom’? Give examples. Write the names and formulae of two organic compounds containing different heteroatoms.

Answer»

(a) A homologous series is a group of organic compounds having similar structures and similar chemical properties in which the successive compounds differ by CH2 group.

Example of Homologous series: All the alkanes have similar structures with single covalent bonds and show similar chemical properties, so they can be grouped together in the form of a homologous series. Homologous series of alkanes: Methane, CH4 ; Ethane, C2H6 ; Propane, C3H8 ; Butane, C4H10 ; Pentane, C5H12 

(b) (i) All the members of the homologous series can be represented by the same general formula.

(ii) Any two adjacent homologues differ by 1 carbon atom and 2 hydrogen atoms in their molecular formulae.

(c) Alkene, CnH2n 

(d) In an organic compound, any atom other than carbon and hydrogen is called a heteroatom. Example: Chlorine (Cl), Bromine (Br), Oxygen (O) Chloromethane – CH3Cl and methanol – CH3OH



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