1.

Account for fluorine shows only one oxidation state, but rest of the halogens shows different oxidation states.

Answer»

Electronic configuration of fluorine is 1s2 2s2 2px2 2py2 2pz2. It has only one orbital half filled and no d-orbital. The orbital cannot be on paired being highly electronegative. It shows only -1 oxidation state as it saturates its valences shell by accepting one electron.

In all other halogen d-orbital are present and ns and p-orbital can be unpaired and the electrons are accommodated in d-orbitals, i.e., showing +3, +5 and +7 oxidation states.



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