1.

Account for the following :(i) XeF2 is linear molecule without a bend.(ii) The electron gain enthalpy with negative sign for fluorine is less than that of chlorine, still fluorine is a stronger oxidizing agent than chlorine.

Answer»

(i) The electron arrangement is trigonal bipyramidal. The shape is linear because the lone pairs prefer the equatorial positions. The molecule XeF2 has 3lone-pairs and 2bond-pairs.

(ii) Low bond dissociation enthalpy and high hydration enthalpy of flourine.



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