1.

Account for the followingPrimary amines have higher boiling point than tertiary amine.The presence of a base is needed in the ammonolysis of alkylhalide.

Answer»
  1. Intermolecular hydrogen bonding exist in primary amine which is not possible in tertiary amine hence primary amine has higher boiling point.
  2. During this reaction HCl is formed which may revert the reaction hence just to get it neutralise base like pyridine or else is used.


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