1.

Acetylene is treatedwith dilutehydrochloricacid inpresenceof HgCI_(2)

Answer»

Solution : Undertheseconditions additio of `H_(2)O` doesnot occuracrossthe doublebond.Instead`CI^(-)` beinga strongernucleophilethan `H_(2)O` , attacks the `PI`- complexformedbetweenacetylene and`HG^(2+)` ionsThisis FOLLOWED byaddition of aprotonto yieldvinylchlorideas shown below :


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